ESI-MS/MS Characterisation of Phenolic Reaction Products of Nitrogen Mustards and N,N-Dialkylaminoethyl-2-Chlorides and Their Rapid Screening by LC-MS/MS in Neutral Loss Scan Mode.

Singh, M Nikita; Harsha, K G; Lakshmi, V V S; Reddy, T Jagadeshwar; Prabhakar, S

doi:10.1002/rcm.70060

ESI-MS/MS Characterisation of Phenolic Reaction Products of Nitrogen Mustards and N,N-Dialkylaminoethyl-2-Chlorides and Their Rapid Screening by LC-MS/MS in Neutral Loss Scan Mode.

2026-06-15, Rapid communications in mass spectrometry : RCM (10.1002/rcm.70060) (online)
M Nikita Singh, K G Harsha, V V S Lakshmi, T Jagadeshwar Reddy, and S Prabhakar (?)

Nitrogen mustards (HN1, HN2 and HN3) and N,N-dialkylaminoethyl-2-chlorides (where alkyl = methyl, ethyl, isopropyl, or propyl) contain reactive chloride bonds that react with phenol in environmental samples to form phenolic reaction products. Identifying these products is crucial for the Chemical Weapons Convention (CWC) verification, as they serve as markers for the presence of scheduled chemicals.

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ESI-MS/MS Characterisation of Phenolic Reaction Products of Nitrogen Mustards and N,N-Dialkylaminoethyl-2-Chlorides and Their Rapid Screening by LC-MS/MS in Neutral Loss Scan Mode.